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Home / Products / Polyurethane Chain Extender / Diol-HCA HER Diol Chain Extender for MDI Polyurethane Systems High Performance PU Elastomers with Excellent Strength Flexibility and Low Shrinkage

Diol-HCA HER Diol Chain Extender for MDI Polyurethane Systems High Performance PU Elastomers with Excellent Strength Flexibility and Low Shrinkage

Diol-HCA HER is a diol-based polyurethane chain extender designed for use with MDI prepolymers in castable, thermoplastic, and millable PU elastomer systems. It provides excellent balance of flexibility, strength, and hardness. The resulting PU elastomers exhibit superior tear strength, initial strength, abrasion resistance, and low shrinkage. HER is ideal for applications requiring high-performance mechanical properties and reliable processing in industrial polyurethane production.
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Diol-HCA HER is a high-performance diol chain extender developed for MDI-based polyurethane elastomer systems. It is specifically recommended for use with MDI prepolymers in the production of castable, thermoplastic, and millable polyurethane elastomers.

In polyurethane chemistry, the choice of chain extender plays a critical role in defining the final properties of the elastomer. Diol-HCA HER is engineered to provide an optimal balance between hard and soft segment structures, resulting in improved mechanical performance and processing behavior. It is particularly suitable for applications requiring both strength and flexibility.

Key Features

  • Diol-based chain extender for controlled reactivity

  • Designed for MDI prepolymer systems

  • Provides excellent balance of hardness and flexibility

  • Improves tear strength and initial mechanical strength

  • Enhances abrasion and cutting resistance

  • Low shrinkage for dimensional stability

  • Suitable for castable, thermoplastic, and millable PU elastomers

Applications

Diol-HCA HER is widely used in:

  • Cast polyurethane elastomers

  • Thermoplastic polyurethane (TPU) systems

  • Millable polyurethane elastomers

  • Industrial rollers and wheels

  • Seals, gaskets, and wear-resistant components

  • Mechanical parts requiring durability and flexibility

Mechanism of Action

As a diol chain extender, Diol-HCA HER reacts with isocyanate groups (–NCO) in MDI prepolymers to form urethane linkages. This reaction contributes to the formation of hard segments within the polyurethane matrix, improving intermolecular interactions and phase separation. The result is enhanced mechanical strength, flexibility, and resistance to wear and deformation.

Performance Advantages

Polyurethane elastomers produced with Diol-HCA HER exhibit:

  • Excellent plasticity and flexibility

  • High tear strength and initial strength

  • Good hardness and load-bearing capacity

  • Strong resistance to cutting and abrasion

  • Low shrinkage for improved dimensional accuracy

Processing & Dosage

  • Used in stoichiometric balance with MDI prepolymers

  • Suitable for casting, extrusion, and milling processes

  • Processing conditions should be optimized based on formulation design

Storage & Handling

Store in a cool, dry environment. Avoid moisture contamination. Keep container tightly sealed. Follow standard industrial safety procedures.

Chemical Component Resorcinol -bis (β-hydroxyethyl) ether
CAS NO.

102-40-9

Appearance White flake solid

Purity

≥ 99%
Hydroxyl Value 550-560mg KOH/g
Initial melting point 83-87℃
Moisture Content ≤0.1%
Product Structure

微信图片_20250912091645


Product Feature

HER is an aromatic glycol chain extender with asymmetric molecular structure.Because the hydroxyethyl group is located at the 1, 3-position (meta-position) of benzene ring, its structural regularity is not as good as that of its isomer HQEE, its melting point is lower than HQEE, and its crystallization rate is slower than HQEE and MOCA. HER melted liquid is not easy to crystallize and solidify during temperature drop. and its lifespan in reaction kettle is longer than butanediol chain extender, which improves the operability. As a diol chain extender product, it is recommended to combine with MDI prepolymer to produce cast, thermoplastic and millable PU elastomer products. The obtained PU elastomer has a lot advantages. Such as excellent plasticity, flexibility, tear strength, initial strength, hardness, cutting resistance and low shrinkage etc.


Application Fields

HER chain-extended polyurethane elastomer can be widely used in various rollers, seals, wear-resistant liners, skateboard wheels, shoe parts, spandex, polyurethane adhesives, coatings, polyurethane flexible foam materials, etc.



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