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What Are Polymer Additives?
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What Are Polymer Additives?

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What are polymer additives?

Polymer additives are things mixed into materials to change or make their properties better. Many industries use these additives to help polymers work better and last longer. About 7% of all polymers in the world have additives that make them stronger, give them color, and help them resist water. Anti-hydrolysis agents are important because they keep materials safe from water damage and help them stay stable. The polymer additives market is getting bigger, as you can see below:

Year

Market Size (USD Billion)

CAGR (%)

2023

56.69

5.7

2032

93.85

5.7

Anti-hydrolysis agents are very important for making materials last longer when they are in tough places.

Key Takeaways

  • Polymer additives help materials get stronger and more flexible. They also make materials resist heat, light, fire, and water.

  • Anti-hydrolysis agents stop water from hurting polymers. They help materials last longer and stay safe in wet and hot places.

  • There are different kinds of anti-hydrolysis agents. Carbodiimide-based agents work best and people use them a lot.

  • Adding anti-hydrolysis agents helps many industries. These include automotive, medical, and consumer products. They keep materials tough and dependable.

  • Using the right polymer additives saves money and cuts down on waste. It also helps make safer and longer-lasting products for daily life.

Types of Polymer Additives

Types of Polymer Additives

Polymers sometimes need help to work well in different places. Manufacturers add polymer additives to make these materials better. Each additive has its own job. They help polymers last longer, stay safe, and work well in many uses.

Stabilizers

Stabilizers keep polymers safe from heat, light, oxygen, and stress. They help materials stay strong for a long time. Heat stabilizers stop damage from high temperatures. Antioxidants stop oxygen from making the material weak. Light stabilizers block UV rays, so things do not fade or break in sunlight. These additives help polymers stay stable in packaging, electronics, and cars.

Note: Stabilizers help materials last longer. This saves money and helps the planet by making less waste.

Plasticizers

Plasticizers make polymers soft and bendy. They fit between polymer chains and let them move more. This makes it easier to shape and mold the material. Plasticizers are used in soft PVC for cables, toys, and medical tubes. There are many kinds, like phthalates, adipates, and bio-based types. The right plasticizer makes materials flexible and easy to use for many things.

Flame Retardants

Flame retardants help materials not catch fire easily. They slow burning, lower heat, and cut down smoke and bad gases. Some use minerals, others use chemicals or natural things like lignin. These additives keep products like furniture, electronics, and buildings safer. Studies show flame retardants delay fire and help form a char, which protects people and things.

Anti-hydrolysis Agents

Anti-hydrolysis agents keep polymers safe from water. Water can break down some materials, like those with ester bonds such as PET and PBT. Anti-hydrolysis agents, like carbodiimide-based ones, react with acids from hydrolysis. This stops damage and keeps the material strong. These agents are needed where polymers face heat and wetness, like in cars, clothes, and packaging. Using anti-hydrolysis additives helps materials last longer and stay stable. These agents work with other additives to keep polymers tough in hard places.

Anti-hydrolysis agents are very important for stopping water damage. They help many products work better today.

Anti-hydrolysis Agent

Mechanism of Anti-hydrolysis

Anti-hydrolysis agents help keep polymers from breaking down when they touch water or moisture. Water can hurt some chemical bonds in materials, especially in ester-based polymers. This causes hydrolysis, which makes the polymer chains weak. When this happens, the material loses strength, flexibility, and looks worse. Anti-hydrolysis agents stop this by reacting with the parts of the polymer that water would attack.

Scientists learned that anti-hydrolysis agents work in a few ways:

  • They react with carboxyl groups or water molecules made during hydrolysis. This forms stable compounds that block more damage.

  • Polycarbodiimide, a common anti-hydrolysis agent, reacts with carboxyl groups. This makes urea-based structures and stops the chain from breaking more.

  • Some agents can even help fix broken polymer chains. This brings back some of the material’s strength.

  • By removing reactive groups, these agents keep the polymer’s molecular weight and strength high, even in wet places.

Anti-hydrolysis agents are important for keeping materials strong and stable, especially where water is common.

Types of Anti-hydrolysis Additives

There are different types of anti-hydrolysis additives used in the polymer industry. The most common are carbodiimide-based agents. These come in both monomeric and polymeric forms. They are popular because they work well and do not cause problems.

Anti-Hydrolysis Agent Type

Key Characteristics and Usage

Market Share / Market Value

Cationic Agents

Stick well and last long; good for surfaces with negative charge

Part of global market ($1.2B in 2024)

Anionic Agents

Stay stable in acid or base; used in coatings and sealants

Included in overall market

Non-ionic Agents

Neutral charge; work with many polymers and resins

Included in overall market

Polymeric Carbodiimide Agents

React with moisture and acids; used in coatings, adhesives, textiles, plastics

$153M in 2023, growing at 8.6% CAGR

Polymeric carbodiimide anti-hydrolysis agents are a fast-growing group. Their market value was about $153 million in 2023. It should almost double by 2030. Big companies like BASF, DSM, and Stahl make these agents, showing they are important.

Bar chart showing anti-hydrolysis agent market share by region: Asia Pacific, North America, Europe, Latin America, and Middle East & Africa.

Carbodiimide-based anti-hydrolysis agents react with carboxylic acids made during hydrolysis of ester-based polymers. This makes stable urea compounds. These slow down more hydrolysis and help the material last longer. Polymeric carbodiimide agents have higher molecular weight and better heat resistance than monomeric types. They also give longer protection and work better in tough places.

Aspect

Monomeric Carbodiimide Agent

Polymeric Carbodiimide Agent

Chemical Mechanism

Reacts with carboxyl groups to form urea compounds, lowering carboxyl content and slowing hydrolysis

Same basic reaction as monomeric agent

Molecular Structure

Has one carbodiimide group

Has many carbodiimide groups, higher molecular weight

Physical Properties

Lower molecular weight; evaporates at about 500℃

Higher molecular weight; better heat resistance, only about 50% evaporates at 500℃

Synthesis and Cost

Easier to make and clean; costs less

Harder to make and clean; costs more

Performance in Polyester

Makes anti-hydrolysis better; makes tensile strength four times higher after aging

Works even better; improves stretch and viscosity

Some commercial anti-hydrolysis agents are Stabaxol® (from RheinChemie), Joncryl® (from BASF), and special products like ST-HT10 and ST-HT13. Stabaxol® is used in polyurethanes, polyamides, PLA, and polyphosphonates. These agents work well at low amounts, usually between 0.1% and 0.7% by weight.

Anti-hydrolysis agents are very important for polymers like PET, PBT, PLA, PU, TPU, and nylons. These materials often face water and heat in real life, which can cause hydrolysis. By adding anti-hydrolysis agents, makers can help these materials stay strong, flexible, and reliable for a long time.

Tip: Pick the right anti-hydrolysis agent based on the polymer type, the place it will be used, and how much stability you need.

Benefits

Durability

Anti-hydrolysis agents help materials last longer. They protect things from water and wet air. Water can damage materials over time. Carbodiimide-based anti-hydrolysis agents help polyester polyurethanes stay strong in wet places. These agents stop acids from breaking down the material. This keeps the inside of the material safe. Many things, like car parts and building sealants, need this strength. Anti-hydrolysis agents make a shield that blocks water from getting inside. This shield helps materials stay tough, bendy, and look good, even after being in rough places for a long time.

Note: Anti-hydrolysis agents help materials last longer. They slow down damage from water and make materials work better outside.

Processing

Making polymers can be hard when there is water or heat. Anti-hydrolysis agents help keep polymers safe during making. They react with carboxylic groups in the polymer. This reaction grabs acids and protects the material. It helps during steps like extrusion and molding. Some agents, like Stabaxol®, help link the polymer chains together. This makes the material stronger while it is made. These agents let makers use cheaper materials and waste less. When processing is better, the final products have fewer problems and are higher quality.

Performance

Anti-hydrolysis agents help polymers work well for a long time. They stop the chains from breaking apart. This keeps the polymer backbone strong. The material does not lose weight or get weak. Polymers with these agents keep over 90% of their strength after being in hot water or wet air. They also stay stretchy and do not break easily. Things like medical devices, packaging, and clothes need this steady performance. Anti-hydrolysis agents also stop the surface from wearing away or cracking. This keeps materials looking new and working well.

  • Anti-hydrolysis agents:

    • Make plastics last longer and stay strong.

    • Help materials resist water and wet air.

    • Keep materials safe in tough places.

    • Work in many things where strength matters.

Applications of Anti-hydrolysis Agents

Anti-hydrolysis agents are used in many industries. They help products last longer in wet or tough places. These agents work in cars, medical devices, and more. They mix into products but do not change how they look. This hidden protection keeps polymers strong for years.

Automotive

Car parts need to be tough in water, heat, and chemicals. Anti-hydrolysis agents are important in engine covers and radiator tanks. They also help hoses and seals stay strong. These parts face high heat and moisture every day. Special polymers use anti-hydrolysis agents to keep their shape. These agents help car parts last longer and not break down. Studies show these agents stop chain breaks and keep parts flexible.

  • Key automotive uses:

    • Engine covers

    • Radiator tanks

    • Hoses and seals

Anti-hydrolysis agents work inside car parts. Drivers do not see them, but they help cars run safely.

Industrial

Factories use machines made from polymers. These machines often work in hot and wet places. Anti-hydrolysis agents protect materials like PLA, PET, and nylon. They stop water from hurting the polymer chains. This keeps machines strong and means fewer repairs. In filters and papermaking cloths, these agents help products last longer and save money.

Polymer Type

Application Area

Benefit from Anti-hydrolysis Agents

PLA

Industrial equipment

Lasts longer, less brittle

PET, PBT

Electrical parts

Works better in heat and steam

Nylon

Gears, bearings

Stays strong and keeps its shape

Medical

Medical devices must be safe and strong in wet places. Anti-hydrolysis agents help by making bonds that resist water. Implants, catheters, and drug delivery systems use these agents. This keeps devices from breaking or losing shape. Anti-hydrolysis agents also help meet safety rules and protect patients.

  • Medical uses:

    • Implants

    • Catheters

    • Drug delivery devices

Consumer Products

Many everyday items use anti-hydrolysis agents to last longer. Sports gear, clothing, and solar panels need these agents. They help products resist water and stay strong for years. In paper machine screens and filters, these agents stop early breakdown and keep things working well.

Anti-hydrolysis agents mix into products during making. They do not change color or feel, but they give long-lasting strength.

Polymer additives help makers build products that are safer and stronger. These additives also help things last longer. They make it easier to shape materials and save money. Additives protect things from heat, light, and fire. Anti-hydrolysis agents help polymers last by stopping water damage. This helps the environment and cuts down on waste.

  • Additives make plastics bendy, bright, and tough.

  • They help companies follow safety and green rules.

Future Trend

Description

Sustainability

Eco-friendly agents are used more in cars and buildings.

Innovation

New science and tests help things last and cost less.

Readers can learn more about how additives change products and help the planet.

FAQ

What are polymer additives used for?

Polymer additives help plastics work better. They make things last longer and stay flexible. They also help materials resist heat and water. Many companies use them to make products safer and stronger.

How do anti-hydrolysis agents protect polymers?

Anti-hydrolysis agents react with bad groups in polymers. They stop water from breaking the chains. This keeps materials strong and safe in wet places.

Can you find polymer additives in everyday products?

Yes! Polymer additives are in car parts, clothes, toys, and medical tools. These additives help things last longer and work well.

Are polymer additives safe for people and the environment?

Most polymer additives follow safety rules. Companies test them to keep people and nature safe. More eco-friendly additives are being used now.

Which polymers need anti-hydrolysis agents the most?

Polymers like PET, PBT, PLA, PU, TPU, and nylon need these agents. These materials often face water and heat, so they need extra help.


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